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UPSC Chemistry Syllabus 2023 for Paper 1 and 2

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UPSC Chemistry Syllabus 2023 for Paper 1 and 2

Edited By Vishnukumar | Updated on May 11, 2023 03:45 PM IST | #BPSC Civil Services

UPSC Chemistry Syllabus 2023 - The UPSC mentioned the UPSC 2023 Chemistry syllabus in the official notification which is released on its official website. The syllabus of UPSC Chemistry 2023 is based on graduation and master's level. The topics as per the UPSC 2023 Chemistry syllabus are atomic structure, states of matter, chemical bonding, thermodynamics, reactions etc. Aspirants who are choosing Chemistry as their optional subject in their mains exam of UPSC CSE can check the UPSC 2023 Chemistry syllabus here.
Download the complete UPSC IAS Chemistry syllabus 2023 pdf - Click here

UPSC Chemistry Syllabus 2023 for Paper 1 and 2
UPSC Chemistry Syllabus 2023 for Paper 1 and 2

The detailed syllabus is mentioned paper-wise for both the papers of the mains exam of UPSC CSE 2023. Chemistry is one of the Optional Subjects with 2 papers (Optional Paper I and Paper II). Apart from the UPSC 2023 Chemistry syllabus, we will share the preparation strategy, tips, and tricks as well as the best books and the IAS exam pattern. Candidates must also check the overall syllabus of UPSC CSE. Check the details syllabus of UPSC Chemistry 2023 here.

UPSC Chemistry Syllabus 2023 - Paper 1

Aspirants picking Chemistry as their optional subject can check the topics and subtopics on which the UPSC Chemistry Syllabus 2023 will be based on.

1. Solid State: Bragg's law: Structures of NaCl, ZnS, CsCl, CaF2; Close packing, radius ratio rules, Crystal systems; Designation of crystal faces, lattice structures and unit cell; X-ray diffraction by crystals; Stoichiometric and nonstoichiometric defects, calculation of some limiting radius ratio values; semiconductors, impurity defects.

2. Chemical bonding: This section will have topics on characteristics of ionic compounds, lattice energy, Ionic bond, Born-Haber cycle; covalent bond and its general characteristics; polarities of bonds in molecules and their dipole moments, Valence bond theory, Molecular orbital theory (LCAO method); the concept of resonance and resonance energy; bonding H2 +, H2 He2 + to Ne2, NO, CO, HF, CN–, bond order, bond strength, Comparison of valence bond and molecular orbital theories, and bond length.

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3. Liquid State: Kelvin equation; Surface tension and surface energy, Wetting and contact angle, capillary action and interfacial tension.

4. Atomic Structure: Heisenberg's uncertainty principle Schrodinger wave equation (time-independent); particle in one- dimensional box, Interpretation of wave function, quantum numbers, hydrogen atom wave functions; Shapes of s, p and d orbitals

5. Electrochemistry: Electrochemical series, Galvanic cells, concentration cells; measurement of e.m.f. of cells and its applications fuel cells and batteries. Processes at electrodes; double layer at the interface; the rate of charge transfer, current density; overpotential; electroanalytical techniques: amperometry, ion-selective electrodes and their use. Debye-Huckel theory of strong electrolytes and Debye-Huckel limiting Law for various equilibrium and transport properties.

6. The Gaseous State and Transport Phenomenon: Equation of state for real gases, Intermolecular interactions, Intermolecular collisions, critical phenomena and liquefaction of gases; collisions on the wall and effusion; Maxwell’s distribution of speeds, Thermal conductivity and viscosity of ideal gases.

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7. Thermodynamics: Second law of thermodynamics; entropy changes in various processes, entropy as a state function, entropy-reversibility and irreversibility, Thermodynamic equation of state; Maxwell relations; Free energy functions; Temperature, volume and pressure dependence of U, H, -T effect and inversion temperature; the relation between equilibrium constant and thermodynamic quantities; criteria for equilibrium, Nernst heat theorem, the introductory idea of the third law of thermodynamics. Work, heat and internal energy; first law of thermodynamics.

8. Phase Equilibria and Solutions: Clausius-Clapeyron equation; phase diagram for a pure substance; phase equilibria in binary systems, partially miscible liquids—upper and lower critical solution temperatures; partial molar quantities, their significance and determination; excess thermodynamic functions and their determination.

9. Bio-inorganic Chemistry: Metal ions in biological systems and their role in ion transport across the membranes (molecular mechanism), oxygen-uptake proteins, cytochromes and ferredoxins.

10. Chemical Kinetics: Study of fast reactions by stop-flow and relaxation methods. Collisions and transition state theories. Differential and integral rate equations for zeroth, first, second and fractional order reactions; Consecutive and chain reactions, Rate equations involving reverse, parallel; effect of temperature and pressure on rate constant, Branching chain and explosions;

11. Surface Phenomena and Catalysis: Absorption from gases and solutions on solid adsorbents; Langmuir and B.E.T. characteristics and mechanism of reaction on heterogeneous catalysts, adsorption isotherms; determination of surface area.

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12. Coordination Chemistry :

(i) Valence bond theory, crystal field theory and its modifications; applications of theories in the explanation of magnetism and electronic spectra of metal complexes, Bonding in the transition of metal complexes.

(ii) Isomerism in coordination compounds; IUPAC nomenclature of coordination compounds; trans effect and its theories; stereochemistry of complexes with 4 and 6 coordination numbers; kinetics of substitution reactions in square-planar complexes; chelate effect and polynuclear complexes; thermodynamic and kinetic stability of complexes.

(iii) EAN rule, Synthesis structure and reactivity of metal carbonyls; carbonyl hydrides and metal nitrosyl compounds, carboxylate anions

(iv) Complexes with aromatic systems, synthesis, alkyne complexes and cyclopentadienyl complexes; structure and bonding in metal olefin complexes, oxidative addition reactions, insertion reactions, coordinative unsaturation, fluxional molecules and their characterization; Compounds with metal-metal bonds and metal atom clusters.

13. Photochemistry: Absorption of light; decay of excited state by different routes; photochemical reactions between hydrogen and halogens and their quantum yields.

14. Main Group Chemistry: Interhalogen compounds, Boranes, phosphazenes and cyclic phosphazene, borazines, silicates and silicones, Sulphur—nitrogen compounds, noble gas compounds.

15. General Chemistry of ‘f’ Block Element: Lanthanides and actinides: separation, oxidation states, magnetic and spectral properties; lanthanide contraction.

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UPSC Chemistry Syllabus 2023 - Paper 2

As per the UPSC Chemistry 2023 Syllabus, the paper 2 will be based on the topics and subtopics as mentioned below:

1. (i) Reaction mechanisms: General methods (both kinetic and non-kinetic) of study of mechanisms or organic reactions: isotopies, method crossover experiment, intermediate trapping, stereochemistry; the energy of activation; kinetic control of reactions and thermodynamic control

(ii) Reactive intermediates: Generation, stability and reactions of Carbenium ions and carbanions, geometry, carbenes, free radicals, benzynes and nitrenes.

(iii) Substitution reactions:—SN 1, SN 2, and SN i, mechanisms; neighbouring group participation; electrophilic and nucleophilic reactions of aromatic compounds including heterocyclic compounds—pyrrole, furan, thiophene and indole.

(iv) Elimination reactions:— E1, E2 and E1cb mechanisms; orientation in E2 reactions—Saytzeff and Hoffmann; Chugaev and Cope eliminations, pyrolytic syn elimination—acetate pyrolysis.

(v) Addition reactions:— ed olefins and carbonyls.

(vi) Reactions and Rearrangements:—(a) Beckmann, Hoffmann, Pinacol-pinacolone, Fries, Baeyer-Villiger, Claisen, Favorskii, Cope, Stevens and Wagner—Meerwein rearrangements.

(b) Aldol condensation, Perkin, Dieckmann, Knoevenagel, Clemmensen, Claisen condensation, Witting, Wolff-Kishner, Cannizzaro and von Richter reactions; Stobbe, benzoin and acyloin condensations; Skraup synthesis, Fischer indole synthesis, Reformatsky reactions and Sandmeyer and Bischler-Napieralski, Reimer-Tiemann.

2. Delocalised Covalent Bonding: Anti-aromaticity; azulenes, aromaticity, annulenes, tropolones, sydnones, fulvenes.

3. Pericyclic reactions: Classification and examples; Woodward-Hoffmann

rules—electrocyclic reactions, cycloaddition reactions [2+2 and 4+2] and sigmatropic

shifts [1, 3; 3, 3 and 1, 5], FMO approach.

4. Synthetic Uses of Reagents: HlO4, CrO3, OsO4, Pb(OAc)4, NBS, SeO2, B2H6, Na-Liquid NH3, NaBH4, LiAIH4, n-BuLi, MCPBA.

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5. Spectroscopy: Principle and applications in structure elucidation :

(i) Rotational—Diatomic molecules; rotational constants and isotopic substitution.

(ii) Vibrational—Diatomic molecules, specific frequencies of functional groups in polyatomic molecules and linear triatomic molecules.

(iii) Electronic—Singlet and triplet states. Conjugated double bonds and conjugated carbonyls Woodward-Fieser rules; Charge transfer spectra.

(iv) Nuclear Magnetic Resonance (1HNMR): Basic principle; coupling constants and chemical shift and spin-spin interaction.

(v) Mass Spectrometry:— McLafferty rearrangement, metastable peak, Parent peak, base peak.

6. (i) Preparation and Properties of Polymers: polyvinyl chloride, polystyrene, Organic polymers polyethene, synthetic, natural rubber, Teflon, nylon and terylene,

(ii) Biopolymers: Structure of proteins, RNA and DNA.

7. Photochemistry: Photochemical reactions of simple organic compounds, excited and ground states, singlet and triplet states, Norrish-Type I and Type II reactions.

UPSC Chemistry Syllabus 2023 - Preparation Tips

Aspirants planning to appear for UPSC IAS 2023, must do it in a better way especially considering the tight competitiveness. Here we are sharing some IAS exam preparation tips that will help candidates in handy and help candidates to score well and qualify for the UPSC 2023 exam. Check the tips here.

  • Only refer to NCERT books to prepare for Chemistry.

  • Make a perfect IAS study plan 2023 and stick to it.

  • UPSC CSE Chemistry requires a high-level preparation level and the difficulty level is of graduation level, hence candidates must start the preparations early.

  • Solve previous year's questions papers of the Chemistry mains exam to know about the type of questions that are asked in the exam. Also, look for UPSC IAS question papers for Chemistry and solve mocks.

  • Do the previous year's UPSC IAS exam analysis 2023, to know about the difficulty level of the exam, and question trends and also to work on your weaker subjects.

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UPSC Chemistry Syllabus 2023 Best Books

From the following table, check the list of best books for UPSC IAS preparation.

Best Books for Chemistry

Best books

Author

NCERT books of Chemistry from 6-12

NCERT

A guide to mechanism in organic chemistry

Peter Sykes

A textbook of environmental chemistry and pollution

S.S. Dara

Organic Chemistry Reactions and reagents

O.P. Agarwal

Principle of physical chemistry

Puri, Sharma & Pathway

A textbook of organic chemistry

Bahl & Ba

Advanced Inorganic Chemistry

J.D. Lee

Extradition of metals, Principle of inorganic chemistry

Puri, Sharma, Jauhar

A textbook of physical chemistry (Vol. – IV)

K.L. Kapoor

Advance physical chemistry

Gurdeep Raj

Also read

Frequently Asked Question (FAQs)

1. Is Chemistry a good subject to be taken as optional?

Yes, but only if you have interest in Chemistry as a subject, or else it can be difficult.

2. How to prepare for Chemistry?

The difficulty level of Chemistry is of graduation level. Hence the preparation takes a lot of time, aspirants must refer to only the best books for preparation.

3. Which is the easiest optional subject for UPSC CSE?

There is no easy or difficult subject, it all depends on your interest and likeability as well as how you can prepare and qualify it. However, maximum candidates pick Sociology, Geography and Public Administration as their optional subjects.

4. What degree is required to apply for UPSC?

To apply for UPSC, aspirants must be a graduate.

5. Who scored the highest marks in UPSC CSE ever?

It was Anudeep Durishetty, she scored 1125 marks out of 2025 in UPSC CSE.

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QA Manager
4 Jobs Available
Quality Controller

A quality controller plays a crucial role in an organisation. He or she is responsible for performing quality checks on manufactured products. He or she identifies the defects in a product and rejects the product. 

A quality controller records detailed information about products with defects and sends it to the supervisor or plant manager to take necessary actions to improve the production process.

3 Jobs Available
Production Manager
3 Jobs Available
Product Manager

A Product Manager is a professional responsible for product planning and marketing. He or she manages the product throughout the Product Life Cycle, gathering and prioritising the product. A product manager job description includes defining the product vision and working closely with team members of other departments to deliver winning products.  

3 Jobs Available
QA Lead

A QA Lead is in charge of the QA Team. The role of QA Lead comes with the responsibility of assessing services and products in order to determine that he or she meets the quality standards. He or she develops, implements and manages test plans. 

2 Jobs Available
Structural Engineer

A Structural Engineer designs buildings, bridges, and other related structures. He or she analyzes the structures and makes sure the structures are strong enough to be used by the people. A career as a Structural Engineer requires working in the construction process. It comes under the civil engineering discipline. A Structure Engineer creates structural models with the help of computer-aided design software. 

2 Jobs Available
Process Development Engineer

The Process Development Engineers design, implement, manufacture, mine, and other production systems using technical knowledge and expertise in the industry. They use computer modeling software to test technologies and machinery. An individual who is opting career as Process Development Engineer is responsible for developing cost-effective and efficient processes. They also monitor the production process and ensure it functions smoothly and efficiently.

2 Jobs Available
QA Manager
4 Jobs Available
AWS Solution Architect

An AWS Solution Architect is someone who specializes in developing and implementing cloud computing systems. He or she has a good understanding of the various aspects of cloud computing and can confidently deploy and manage their systems. He or she troubleshoots the issues and evaluates the risk from the third party. 

4 Jobs Available
Azure Administrator

An Azure Administrator is a professional responsible for implementing, monitoring, and maintaining Azure Solutions. He or she manages cloud infrastructure service instances and various cloud servers as well as sets up public and private cloud systems. 

4 Jobs Available
Computer Programmer

Careers in computer programming primarily refer to the systematic act of writing code and moreover include wider computer science areas. The word 'programmer' or 'coder' has entered into practice with the growing number of newly self-taught tech enthusiasts. Computer programming careers involve the use of designs created by software developers and engineers and transforming them into commands that can be implemented by computers. These commands result in regular usage of social media sites, word-processing applications and browsers.

3 Jobs Available
Product Manager

A Product Manager is a professional responsible for product planning and marketing. He or she manages the product throughout the Product Life Cycle, gathering and prioritising the product. A product manager job description includes defining the product vision and working closely with team members of other departments to deliver winning products.  

3 Jobs Available
Information Security Manager

Individuals in the information security manager career path involves in overseeing and controlling all aspects of computer security. The IT security manager job description includes planning and carrying out security measures to protect the business data and information from corruption, theft, unauthorised access, and deliberate attack 

3 Jobs Available
ITSM Manager
3 Jobs Available
Automation Test Engineer

An Automation Test Engineer job involves executing automated test scripts. He or she identifies the project’s problems and troubleshoots them. The role involves documenting the defect using management tools. He or she works with the application team in order to resolve any issues arising during the testing process. 

2 Jobs Available
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